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• W2068183978 abstract "Abstract Chromium oxide (CrO3) was vaporized from a Knudsen cell into the ionization chamber of a time-of-flight mass spectrometer. The ions CrO3−, (CrO3)2− and (CrO3)3− were observed. The dimer and trimer showed resonance capture processes at approximately O eV electron energy. In addition, the dimer ion was formed by dissociative resonance capture at three resonances having onsets at 2·8, 3·8 and 4·8 eV. These are attributed to formation of (CrO3)2− from the neutral pentamer, tetramer and trimer respectively. When the appearance potentials are corrected for excess energy the electron affinity of (CrO3)2 is found to be 1·6 ± 0·3 eV. The trimer ion exhibited two dissociative resonance capture peaks at 2·7 and 4·1 eV attributable to the formation of (CrO3)3− from the pentomer and tetramer respectively. Excess energy could not be measured, but the electron affinity was estimated to be approximately 1·8 eV." @default.
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• W2068183978 date "1975-05-01" @default.
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• W2068183978 title "Low energy electron attachment to gaseous chromium oxides" @default.
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• W2068183978 doi "https://doi.org/10.1016/0022-1902(75)80452-0" @default.
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