Matches in SemOpenAlex for { <https://semopenalex.org/work/W2068192238> ?p ?o ?g. }
- W2068192238 endingPage "202" @default.
- W2068192238 startingPage "194" @default.
- W2068192238 abstract "Phenoxo bridged tetranuclear Cu(II) and dinuclear Zn(II) complexes are synhesized namely, Cu4[(L)2(OCH3)2] (1) and Zn2(HL)2 (2) (H3L = [(HOC6H2CH3){2,6-(CHN–NC(OH)(C6H5))(CHN–NC(OH)(C6H5))}]) and characterized by FTIR, UV–Vis, 1H NMR, fluorescence and mass spectrometry. Single crystal X-ray diffraction analysis of 1 shows that the Cu atom possesses a square pyramid environment via bridging of ‘phenolato’-O and ‘enolato’-O of the ligand, additional bridging of ‘methanolato’-O of coordinated CH3OH and monodentate coordination of imine-N. The EPR spectrum of 1 are characterized by g‖ = 2.286, A‖ = 169 × 10−4 cm−1, g⊥ = 2.068, A⊥ = 17 × 10−4 cm−1 (298 K) and g‖ = 2.283, A‖ = 178 × 10−4 cm−1, g⊥ = 2.072, A⊥ = 15 × 10−4 cm−1 (77 K). The study of the variable temperature magnetic properties agrees with a predominant intramolecular antiferromagnetic coupling (2J = −186.5 cm−1), rendering a ground state of S = 0." @default.
- W2068192238 created "2016-06-24" @default.
- W2068192238 creator A5018155569 @default.
- W2068192238 creator A5039513933 @default.
- W2068192238 creator A5039696026 @default.
- W2068192238 creator A5049029899 @default.
- W2068192238 creator A5049732702 @default.
- W2068192238 creator A5078180325 @default.
- W2068192238 date "2014-03-01" @default.
- W2068192238 modified "2023-09-23" @default.
- W2068192238 title "Phenoxo bridged tetranuclear copper(II) and dinuclear zinc(II) complexes of 2,6-diformyl-4-methylphenol-di(benzoylhydrazone): Synthesis, structure, spectra and magnetism" @default.
- W2068192238 cites W1964603841 @default.
- W2068192238 cites W1969317835 @default.
- W2068192238 cites W1971834299 @default.
- W2068192238 cites W1972310517 @default.
- W2068192238 cites W1975098194 @default.
- W2068192238 cites W1975153728 @default.
- W2068192238 cites W1976445791 @default.
- W2068192238 cites W1976984963 @default.
- W2068192238 cites W1977441978 @default.
- W2068192238 cites W1981857846 @default.
- W2068192238 cites W1981957089 @default.
- W2068192238 cites W1985469967 @default.
- W2068192238 cites W1986770190 @default.
- W2068192238 cites W1992040740 @default.
- W2068192238 cites W1993396656 @default.
- W2068192238 cites W1994797015 @default.
- W2068192238 cites W2003320946 @default.
- W2068192238 cites W2003889571 @default.
- W2068192238 cites W2004112993 @default.
- W2068192238 cites W2008470511 @default.
- W2068192238 cites W2008553568 @default.
- W2068192238 cites W2008584788 @default.
- W2068192238 cites W2008805209 @default.
- W2068192238 cites W2015151362 @default.
- W2068192238 cites W2016968085 @default.
- W2068192238 cites W2017294748 @default.
- W2068192238 cites W2019715736 @default.
- W2068192238 cites W2020631205 @default.
- W2068192238 cites W2021590656 @default.
- W2068192238 cites W2022508805 @default.
- W2068192238 cites W2023417157 @default.
- W2068192238 cites W2029963614 @default.
- W2068192238 cites W2033237010 @default.
- W2068192238 cites W2033957852 @default.
- W2068192238 cites W2039806200 @default.
- W2068192238 cites W2042404011 @default.
- W2068192238 cites W2042713051 @default.
- W2068192238 cites W2044596918 @default.
- W2068192238 cites W2045894490 @default.
- W2068192238 cites W2050707336 @default.
- W2068192238 cites W2051377849 @default.
- W2068192238 cites W2052562606 @default.
- W2068192238 cites W2052668662 @default.
- W2068192238 cites W2053286356 @default.
- W2068192238 cites W2053711548 @default.
- W2068192238 cites W2059514874 @default.
- W2068192238 cites W2060520417 @default.
- W2068192238 cites W2062341710 @default.
- W2068192238 cites W2065325674 @default.
- W2068192238 cites W2068976434 @default.
- W2068192238 cites W2069130005 @default.
- W2068192238 cites W2071079307 @default.
- W2068192238 cites W2080964382 @default.
- W2068192238 cites W2082767443 @default.
- W2068192238 cites W2088547762 @default.
- W2068192238 cites W2090155847 @default.
- W2068192238 cites W2090747689 @default.
- W2068192238 cites W2092308338 @default.
- W2068192238 cites W2105249240 @default.
- W2068192238 cites W2113629638 @default.
- W2068192238 cites W2130552689 @default.
- W2068192238 cites W2170667318 @default.
- W2068192238 cites W2315695992 @default.
- W2068192238 cites W2330721092 @default.
- W2068192238 cites W277762786 @default.
- W2068192238 cites W3137857241 @default.
- W2068192238 doi "https://doi.org/10.1016/j.ica.2014.01.013" @default.
- W2068192238 hasPublicationYear "2014" @default.
- W2068192238 type Work @default.
- W2068192238 sameAs 2068192238 @default.
- W2068192238 citedByCount "11" @default.
- W2068192238 countsByYear W20681922382015 @default.
- W2068192238 countsByYear W20681922382016 @default.
- W2068192238 countsByYear W20681922382017 @default.
- W2068192238 countsByYear W20681922382018 @default.
- W2068192238 countsByYear W20681922382020 @default.
- W2068192238 countsByYear W20681922382021 @default.
- W2068192238 crossrefType "journal-article" @default.
- W2068192238 hasAuthorship W2068192238A5018155569 @default.
- W2068192238 hasAuthorship W2068192238A5039513933 @default.
- W2068192238 hasAuthorship W2068192238A5039696026 @default.
- W2068192238 hasAuthorship W2068192238A5049029899 @default.
- W2068192238 hasAuthorship W2068192238A5049732702 @default.
- W2068192238 hasAuthorship W2068192238A5078180325 @default.
- W2068192238 hasConcept C103319777 @default.
- W2068192238 hasConcept C115624301 @default.
- W2068192238 hasConcept C116569031 @default.