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- W2068196790 abstract "Abstract One pot synthesis of a purely inorganic framework of azido-lead(II) complex with molecular formula [Pb 3 (N 3 ) 6 ] n has been made by using 5-aminotetrazole (5-ATZ) ligand as starting material. X-ray single crystal structure determination revealed the presence of two types of Pb-centers (Pb1 and Pb2). One-dimensional propagation of Pb1 centers with azide segment gives an infinite zig–zag 1D chain along c -axis. 2D sheet is formed along bc - and ac -plane with the 1D chain. It is interesting to identify another infinite 1D chain along a -axis by connecting Pb2 centers via azide linkage. The compound displays an overall 3D structure. All the connectivity of azide in complex 1 show exclusive end-to-end ( i.e ., μ -1,3) binding." @default.
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- W2068196790 date "2011-03-01" @default.
- W2068196790 modified "2023-09-23" @default.
- W2068196790 title "3D purely inorganic lead-azide coordination polymer constructed by exclusive end-to-end azido binding" @default.
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- W2068196790 doi "https://doi.org/10.1016/j.molstruc.2011.01.023" @default.
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