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• W2068197783 abstract "The addition of an achiral crown ether (18-crown-6) to a cyclodextrin-based separation can significantly affect the capillary electrophoresis (CE) enantioresolution of organic racemates that contain a primary amine functional group. In most cases an enhancement of the enantioseparation was observed. However, there are also cases where the addition of 18-crown-6 was detrimental to a cyclodextrin-based CE enantioseparation. The effect of concentration of the two complexing additives as well as the effect of pH and added potassium ion were examined. A specific three-body complex involving simultaneous, dual inclusion complex formation can be used to explain both the enhanced and diminished enantioselectivities observed when 18-crown-6 is added to the run buffer." @default.
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• W2068197783 date "1998-01-01" @default.
• W2068197783 modified "2023-09-26" @default.
• W2068197783 title "Mechanism of capillary electrophoresis enantioseparations using a combination of an achiral crown ether plus cyclodextrins" @default.
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• W2068197783 doi "https://doi.org/10.1016/s0021-9673(97)00826-1" @default.
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