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- W2068199995 abstract "A theoretical expression for the magnetic susceptibility and anisotropy of an Mn (111) ion having trigonal symmetry in octahedral trisacetylacetonato manganese have been derived on the basis of the more general molecular orbital method of Van Vleck, Stevens, and Bose et al., considering quantum mechanical tunnelling which links equivalent vibronic states of the Jahn-Teller ion. Attempts have been made to fit the experimental data of optical absorption and magnetic susceptibility with a unique set of parameters in the theoretical expressions at all temperatures. From this an estimate of the parameters which describe the Jahn-Teller potential is made. Ein theoretischer Ausdruck für die magnetische Suszeptibilität und Anisotropie eines Mn (111)-Ions mit trigonaler Symmetrie in oktaedrischem Mangan-Triazetylazetonat wurde auf der Grundlage einer allgemeineren Molekülorbitalmethode von Van Vleck, Stevens und Bose et al. abgeleitet, wobei quantenmechanisches Tunneln, das äquivalente Schwingungszustände des Jahn-Teller-Ions koppelt, berücksichtigt wird. Es wird der Versuch gemacht, die experimentellen Ergebnisse der optischen Absorption und magnetischen Suszeptibilität mit einem einzigen Parametersatz an die theoretischen Ausdrücke für alle Temperaturen anzupassen. Daraus werden Parameter, die das Jahn-Teller-Potential beschrieben, berechnet." @default.
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- W2068199995 title "Role of Jahn-Teller Effect in the Ligand Field Theory of Octahedrally Coordinated Trisacetylacetonato Manganese" @default.
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- W2068199995 doi "https://doi.org/10.1002/pssb.2220430206" @default.
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