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- W2068200636 abstract "White phosphorus in a finely divided form reacts with sodium alkanethiolates in the presence of the corresponding thiol and an excess of tetrachloromethane to give high yields of the trithioite, (RS)3P, and trichloromethane. When a stoicheiometric quantity of sodium ethanethiolate was used, triethyl phosphorotrithioite together with diethyl phosphorochloridodithioite and diethyl trichloromethylphosphonodithioite were isolated as major products. A minor side reaction between thiolate ions and tetrachloromethane leads to the formation of dialkyl disulphide and trialkyl trithio-orthoformate. A reaction scheme for the formation of these products is suggested." @default.
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- W2068200636 date "1979-01-01" @default.
- W2068200636 modified "2023-09-25" @default.
- W2068200636 title "The reaction of elemental phosphorus with alkanethiolates in the presence of tetrachloromethane" @default.
- W2068200636 doi "https://doi.org/10.1039/p19790001799" @default.
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