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- W2068201714 abstract "By carrying out controlled potential electrolysis on very dryethylsulphoxide solutions of UO22+ nitrate under an argon atmosphere, sufficient quantities of UO2++ could be prepared for electronic spectral investigation. Disproportionation of this stable species into UO22+ and UO2 occurred, but the half-life of about one hr for UO22+ gave sufficient time for measurement to be made. In the region 6100–20,000 cm−1 three maxima were observed. The main peak occurred at 6620 cm−1 (ϵ ≈ 87) and the other two maxima of roughly one-tenth the intensity were observed at 12,940 cm−1 and 15,080 cm−1. The main peak is assignable as the 2F52→2F72 transition." @default.
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- W2068201714 date "1968-08-01" @default.
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- W2068201714 title "Studies of dioxouranium(V) in dimethylsulphoxide" @default.
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- W2068201714 doi "https://doi.org/10.1016/0022-1902(68)80356-2" @default.
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