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- W2068206575 abstract "The diffusion coefficient of Li-ions (DLi+) within carbon-rich silicon-oxycarbide ceramic anodes of specific chemical composition SiO0.95C3.72 is determined by potentiostatic and galvanostatic intermittent titration technique (PITT, GITT) and electrochemical impedance spectroscopy (EIS). The estimated values for DLi+ range between 10−9 and 10−11 cm2 s−1, dependent on the applied method. The observed variation of DLi+ is in a comparable range as reported for disordered carbons, well reflecting the Li-ion storage in the segregated free carbon phase in the amount of about 43 wt-% within the SiOC microstructure. However, in contrast to graphite and disordered carbons, the diffusion coefficient of lithium within carbon-rich SiOC is less potential dependent. This feature is discussed with respect to the particular morphology of the free carbon phase." @default.
- W2068206575 created "2016-06-24" @default.
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- W2068206575 date "2014-01-01" @default.
- W2068206575 modified "2023-10-18" @default.
- W2068206575 title "Determination of the chemical diffusion coefficient of Li-ions in carbon-rich silicon oxycarbide anodes by electro-analytical methods" @default.
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- W2068206575 doi "https://doi.org/10.1016/j.electacta.2013.10.184" @default.
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