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• W2068209232 endingPage "4633" @default.
• W2068209232 startingPage "4627" @default.
• W2068209232 abstract "Currently there is no material clinically available as a long-term vitreous substitute. In this study, an in-situ gelation system based on α-poly(ethylene glycol) methacrylate (α-PEG-MA) and a redox-initiated radical polymerization/crosslinking reaction was evaluated for this purpose. Ammonium persulfate (APS) and N,N,N′,N′-tetramethyl ethylene diamine (TMEDA) were used as initiators. The gelation time, rheological properties, reaction kinetics and swelling profiles were studied in detail and the system with 10 wt% of α-PEG-MA and 8 mM APS/TMEDA was chosen as the optimal material for in vivo studies. Using the rabbit as the animal model, we showed that the system did form a space-filling and transparent gel in the vitreous cavity, and the inflammation response could be controlled to an acceptable level." @default.
• W2068209232 created "2016-06-24" @default.
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• W2068209232 date "2014-09-01" @default.
• W2068209232 modified "2023-09-27" @default.
• W2068209232 title "Evaluation of a redox-initiated in situ hydrogel as vitreous substitute" @default.
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• W2068209232 doi "https://doi.org/10.1016/j.polymer.2014.07.031" @default.
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