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- W2068223586 abstract "The i.r. Raman spectra of gaseous vinylsilane and vinylsilane-SiD3 have been recorded. The vibrational assignments for vinylsilane have been clarified by inclusion of new Raman data, and normal coordinate calculations have been performed. Two series of summation and difference bands arising from combinations between the SiH3 stretching vibrations and the low-frequency torsion have been observed in the i.r. spectrum at moderately high resolution. A similar series of combination bands with the symmetric SiH3 deformation and an SiD3 stretch have also been observed. The bands are fully consistent with one another, and the frequencies of the v = 1 ← 0, 2 ← 1 and 3 ← 2 torsional transitions have been deduced to be 132, 121 and 106 cm−1 for the normal isotope and 109, 102 and 94 cm−1 for the SiD3 isotopic modification." @default.
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- W2068223586 date "1985-01-01" @default.
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- W2068223586 title "Vibrational spectra, normal coordinate analysis and torsional barrier of vinylsilane" @default.
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- W2068223586 doi "https://doi.org/10.1016/0584-8539(85)80093-3" @default.
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