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• W2068243370 abstract "A formal partial wave analysis of the third-order energy for the interaction of three non-degenerate S-state atoms is used to identify those non-additive terms which, in the limit of negligible charge overlap between the interacting atoms, reduce to the usual long-range expanded form of the triple-dipole energy. Pseudo-state techniques are used to evaluate these terms, both with and without the inclusion of charge-overlap effects, over a range of interatomic separations and angles for the interaction of three ground-state hydrogen atoms. These results are used as a model to discuss the way in which charge-overlap effects modify the usual long-range result for the triple-dipole energy. In addition to the familiar modification of the radial dependence of the interaction energy, charge-overlap effects are found to give rise to a modification of the angular dependence; the latter effect has no analogue in two-atom interactions. The significance of these results is discussed briefly." @default.
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• W2068243370 date "1974-12-01" @default.
• W2068243370 modified "2023-09-28" @default.
• W2068243370 title "Charge-overlap effects in the non-additive triple-dipole interaction" @default.
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• W2068243370 doi "https://doi.org/10.1080/00268977400102711" @default.
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