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- W2068267124 abstract "The influence of transition metal (Cr, Mn, Fe, Co, Ni and Cu) on the hydrogenation properties of chloronitrobenzene (CNB) over Pt/TiO2 catalyst has been studied in ethanol at 303 K and normal pressure. The hydrogenation of CNB can be carried out over Pt/TiO2 catalyst. The order of the hydrogenation rate of CNB is m>p>o, and the yield of chloroaniline (CAN) is p>m>o. The effect of transition metal may be interpreted by electronic effect. Electron deficient species of the second element promote the specific rate constant turnover frequency (TOF) expressed on a per surface Pt atom by activating the nitrogen–oxygen bond. The conversion of CNB is over 99% and chloroaniline is main product on the hydrogenation of CNB over PtM/TiO2 catalysts. PtFe/TiO2 catalyst shows the best selectivity of CNB to CAN, and 98.0 mol% for p-CAN, 98.5 mol% for m-CAN and 98.7 mol% for o-CAN, respectively. Both catalytic activity and yield of p-CAN increase with addition of Fe over Pt/TiO2 on the hydrogenation of p-CNB." @default.
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- W2068267124 date "2004-02-01" @default.
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- W2068267124 title "Effect of transition metal (Cr, Mn, Fe, Co, Ni and Cu) on the hydrogenation properties of chloronitrobenzene over Pt/TiO2 catalysts" @default.
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- W2068267124 doi "https://doi.org/10.1016/j.molcata.2003.07.018" @default.
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