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- W2068274799 abstract "The O–H stretching absorption (νO–H) spectra of some keto-alcohols have been examined. The νO–H shift to the lower frequency due to the intramolecular O–H··· bonding can roughly be correlated to the geometry of the hydroxyl group relative to the n-electrons on the carbonyl oxygen. When the bonding is forbidden because of the conformational restriction, a weaker interaction between the hydroxyl group and the π-electrons on the carbonyl group is observable as the lower shift of the νO–H by 10–30 cm−1 as far as the conformation is favorable for the interaction." @default.
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- W2068274799 date "1968-01-01" @default.
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- W2068274799 title "Intramolecular Interaction between Hydroxyl Group and Carbonyl Moiety in Keto-alcohols" @default.
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- W2068274799 doi "https://doi.org/10.1246/bcsj.41.176" @default.
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