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• W2068277247 abstract "Experimental data and thermodynamic considerations show that direct reaction of the elements can produce pure FeS2. Polycrystalline iron was converted in a sulphur atmosphere. The iron sulphide samples were characterized with scanning electron microscopy, X-ray diffractometry and small-spot electron spectroscopy for chemical analysis. Based on these results and on thermodynamic calculations employing literature data, a model for layer growth involving a complex mechanism is proposed. In a first step, FexS is formed chemoepitaxially followed by a conversion to FeS2 by a chemoendotaxial reaction with sulphur. Grain boundaries play a decisive role in the growth process." @default.
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• W2068277247 date "1992-10-01" @default.
• W2068277247 modified "2023-09-30" @default.
• W2068277247 title "Thermodynamic aspects of pyrite film formation by sulphur conversion of iron" @default.
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• W2068277247 doi "https://doi.org/10.1016/0040-6090(92)90721-m" @default.
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