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- W2068296860 abstract "Butadiene, 1,3-pentadiene, 2-methyl-1,3-pentadiene and 4-methyl-1,3-pentadiene have been polymerized with MAO/Cp′VCl2·2PEt3 and MAO/Cp2VCl (Cp′ C5H4Me, Cp C5H5). Polymers, predominantly cis-1,4, have been obtained from butadiene and pentadiene, a polymer with a mixed cis/trans structure has been obtained from 2-methyl-1,3-pentadiene, while 4-methyl-1,3-pentadiene gave a predominantly 1,2 polymer. Cp′VCl2·2PEt3/MAO was found to be particularly active. The different stereospecificities of the systems are discussed with respect to other soluble vanadium systems." @default.
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- W2068296860 date "1996-01-01" @default.
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- W2068296860 title "Polymerization of 1,3-dienes with catalysts based on mono- and bis-cyclopentadienyl derivatives of vanadium" @default.
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- W2068296860 doi "https://doi.org/10.1016/0032-3861(96)81112-8" @default.
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