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• W2068302989 abstract "Degradation of TiO2-based ceramic capacitors was observed after hydrogen incorporation on the termination electrodes of the capacitors via electrolysis of water. Fourier-transform infrared (FTIR) absorption spectra analysis of polished rutile single crystals clearly showed that hydrogen was incorporated into the TiO2 lattice through the treatment. Hydrogen reduces Ti4+ to Ti3+ and increases the concentration of charge carriers. The degradation was found to exhibit a strong dependence on time at room temperature. The degraded properties were spontaneously recovered through an aging process, showing a spontaneous recovery unique to TiO2-based ceramic capacitors. It is proposed that hydrogen is metastable in TiO2 and that hydrogen-induced degradation has different stabilities among various oxide-based components and devices." @default.
• W2068302989 created "2016-06-24" @default.
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• W2068302989 date "2003-12-30" @default.
• W2068302989 modified "2023-10-18" @default.
• W2068302989 title "Spontaneous recovery of hydrogen-degraded TiO2 ceramic capacitors" @default.
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• W2068302989 doi "https://doi.org/10.1063/1.1637942" @default.
• W2068302989 hasPublicationYear "2003" @default.
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