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- W2068316502 abstract "A new type of a phenolic self-crosslinking resin was prepared by the oxidation of the hydroquinone–phenol formaldehyde resins with chloric acid. The chemical behaviors of the resin in the process of self-curing occurred by heating were followed by DTA and the infrared spectral analysis. Some physical properties such as glass transition temperature and the extent of crosslinking were examined for the cured resins by the swinging beam method and the solvent extraction method, respectively, and the excellent thermal rigidity of the cured resins was compared with that of the conventional phenolic resins cured with hexamethylenetetramine. The radical reaction mechanism in the self-crosslinking of the resin is proposed from the results obtained in the reactions of p-benzo-quinone with some model phenolic compounds and that obtained in the observation of ESR spectrum of the quinhydrone system." @default.
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- W2068316502 date "2007-03-07" @default.
- W2068316502 modified "2023-10-16" @default.
- W2068316502 title "Studies on phenolic resins. VII. The preparation of a new type of self-crosslinking phenolic resin and the reaction mechanism of the crosslinking" @default.
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- W2068316502 doi "https://doi.org/10.1002/polc.5070160346" @default.
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