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- W2068319605 abstract "Oriented PbTiO3 thin films with different average grain sizes were prepared by the sol-gel method on (111) PtSi substrates. The phase transitions in the films were investigated by using high-temperature XRD measurements. It was found that the phase transition from tetragonal to cubic in the film of grain size ~ 210 nm occurs at about 480 °C, whereas it occurs at around 460 °C in the film of grain size ~ 130 nm. The transition is reversible but with about 20 °C hysteresis between cooling and heating. The Curie temperatures Tc measured for both films are lower than that of the bulk. The Tc decreases with grain size. Although an abrupt 90 °-domain absence occurs between the two films, no major change in the Tc was observed. In addition, it was observed that the change in the c-parameter with temperature is almost the same in both heating and cooling cycles whereas the a-value exhibits hysteresis. This results just the reverse of those reported previously." @default.
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- W2068319605 date "1998-02-01" @default.
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- W2068319605 title "Grain size effect on the phase transitions in oriented PbTiO3 thin films deposited by the sol-gel method on (111)" @default.
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- W2068319605 doi "https://doi.org/10.1016/s0167-577x(97)00128-6" @default.
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