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- W2068363410 abstract "The infrared spectrum between 33 and 400 cm−1 has been examined in the vapor and liquid phases for the following 26 compounds: o-, m-, and p-F, Cl, Br, and CH3 benzaldehydes; pyridine-2-, -3-, and 4-aldehydes; acetophenone and its o-, m-, and p- F derivatives; furan-2-aldehyde; and several monofluorostyrenes and -nitrobenzenes. Torsional frequencies were sought, and have been assigned for all but the last two groups of compounds. For all the meta-substituted benzaldehydes, for a few of the ortho ones, and for furan-2-aldehyde evidence has been found for the presence of two rotational isomers in the vapor. The parameters V1 and V2 of an approximate potential function for the internal rotation have been evaluated. In the meta benzaldehydes the O-cis rotamer is the more stable one, whereas in the ortho compounds and in furan-2-aldehyde it is the O-trans one. For meta-fluorobenzaldehyde a temperature-dependence study of some bands in the mid-infrared has confirmed the existence of two rotamers, and has given 0.5 kcal/mole as an approximate value for their energy difference in CDCl3 solution." @default.
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- W2068363410 date "1967-04-01" @default.
- W2068363410 modified "2023-09-27" @default.
- W2068363410 title "Torsional frequencies in the far infrared—V. Torsions around the CC signle bond in some benzaldehydes, furfural, and related compounds" @default.
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- W2068363410 doi "https://doi.org/10.1016/0584-8539(67)80016-3" @default.
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