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- W2068372720 abstract "Electrochemically active lithium sulfide-carbon (Li 2 S-C) composite positive electrodes, prepared by the spark plasma sintering process, were applied to all-solid-state lithium secondary batteries with a Li 3 PO 4 -Li 2 S-SiS 2 glass electrolyte. The electrochemical tests demonstrated that In/Li 2 S-C cells showed the initial charge and discharge capacities of ca. 1010 and 920 mAh g -1 -Li 2 S, respectively, which showed higher discharge capacity and coulombic efficiency (ca. 91%) than the Li/Li 2 S-C cells with nonaqueous liquid electrolytes (ca. 200-380 mAh g -1 -Li 2 S and ca. 27%, respectively). The ex situ S K-edge X-ray absorption fine structure measurements suggested the appearance and disappearance of elemental sulfur in the positive electrodes after charging and discharging, respectively, indicating that the ideal electrochemical reaction Li 2 S ⇔ 2Li + S proceeded in the present all-solid-state cells. Such ideal electrochemical reaction, due probably to the suppression of the dissolution of Li 2 S in the form of polysulfides into the electrolytes, would result in higher coulombic efficiency and discharge capacity as compared with those of the liquid-electrolyte cells." @default.
- W2068372720 created "2016-06-24" @default.
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- W2068372720 date "2010-01-01" @default.
- W2068372720 modified "2023-10-16" @default.
- W2068372720 title "All-Solid-State Lithium Secondary Battery with Li[sub 2]S–C Composite Positive Electrode Prepared by Spark-Plasma-Sintering Process" @default.
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- W2068372720 doi "https://doi.org/10.1149/1.3486083" @default.
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