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- W2068386054 abstract "The reaction of [CH2(PPh2═NSiMe3)(PPh2═E)] (E = S (1), NSiMe3 (2)) with Mg(Bun)2 in refluxing toluene afforded the magnesium bis(phosphoranyl)methanediide complexes [{(PPh2═NSiMe3)(PPh2═E)}CMg]2 (E = S (3), NSiMe3 (4)), respectively. The X-ray structures and DFT calculations of 3 and 4 show that they are bimetallic methanediide complexes of magnesium containing a strong Mg−Cmethanediide electrostatic bonding. Treatment of 4 with water in toluene gave 2 and the magnesium hydroxide complex [HC(PPh2═NSiMe3)2Mg(μ−OH)]2 (5), confirmed by X-ray crystallography. The reaction of 1 with AlMe3 in refluxing toluene afforded the aluminum bis(phosphoranyl)methanediide complex [{(PPh2═NSiMe3)(PPh2═S)}CAlMe]2 (6). The X-ray structure of 6 shows that a methanediide carbon is bonded to one aluminum atom. DFT calculations of 6 demonstrate that Al−Cmethanediide is highly polar with weak covalent bonding, consistent with the topological analysis of electron densities of 6." @default.
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- W2068386054 date "2010-01-21" @default.
- W2068386054 modified "2023-10-10" @default.
- W2068386054 title "Synthesis and Characterization of Magnesium and Aluminum Bis(phosphoranyl)methanediide Complexes" @default.
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- W2068386054 doi "https://doi.org/10.1021/om900985f" @default.
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