Matches in SemOpenAlex for { <https://semopenalex.org/work/W2068393934> ?p ?o ?g. }
Showing items 1 to 85 of
85
with 100 items per page.
- W2068393934 endingPage "3522" @default.
- W2068393934 startingPage "3518" @default.
- W2068393934 abstract "Vapor-phase oxidation of butadiene, 2,5-dihydrofuran and furan over supported molybdena catalysts has been investigated with reference to the reaction mechanism and the rate-determining step of maleic anhydride formation from butadiene. Formation of maleic anhydride during the oxidation of butadiene was found to follow two reaction mechanisms, (a) via 2,5-dihydrofuran and furan, and (b) via 2,5-dihydrofuran but not via furan. The energy barrier for the addition of oxygen species to adsorbed butadiene or furan is very high, i.e., 28.9 or 21.9kcal/g-mol, respectively, as compared to that for the oxidative dehydrogenation of the intermediate compounds such as 2,5-dihydrofuran. Formation of 2,5-dihydrofuran is rate-determining in these mechanisms during the oxidation of butadiene to maleic anhydride. The second mechanism plays a more important role in maleic anhydride formation at low temperatures, the role of the first mechanism increasing with a rise in the reaction temperature." @default.
- W2068393934 created "2016-06-24" @default.
- W2068393934 creator A5064441414 @default.
- W2068393934 creator A5090001436 @default.
- W2068393934 date "1975-12-01" @default.
- W2068393934 modified "2023-09-27" @default.
- W2068393934 title "Competition of the Two Reaction Mechanisms of Maleic Anhydride Formation in Vapor-Phase Oxidation of Butadiene over Supported Molybdena Catalysts" @default.
- W2068393934 cites W1971307231 @default.
- W2068393934 cites W2010607635 @default.
- W2068393934 cites W2013670916 @default.
- W2068393934 cites W2014400618 @default.
- W2068393934 cites W2025384054 @default.
- W2068393934 cites W2316559477 @default.
- W2068393934 cites W2320888408 @default.
- W2068393934 cites W2325240527 @default.
- W2068393934 cites W2327383816 @default.
- W2068393934 cites W2329740031 @default.
- W2068393934 cites W2331078909 @default.
- W2068393934 cites W3098294301 @default.
- W2068393934 doi "https://doi.org/10.1246/bcsj.48.3518" @default.
- W2068393934 hasPublicationYear "1975" @default.
- W2068393934 type Work @default.
- W2068393934 sameAs 2068393934 @default.
- W2068393934 citedByCount "18" @default.
- W2068393934 crossrefType "journal-article" @default.
- W2068393934 hasAuthorship W2068393934A5064441414 @default.
- W2068393934 hasAuthorship W2068393934A5090001436 @default.
- W2068393934 hasBestOaLocation W20683939341 @default.
- W2068393934 hasConcept C119889771 @default.
- W2068393934 hasConcept C121332964 @default.
- W2068393934 hasConcept C150394285 @default.
- W2068393934 hasConcept C15920480 @default.
- W2068393934 hasConcept C161790260 @default.
- W2068393934 hasConcept C178790620 @default.
- W2068393934 hasConcept C185592680 @default.
- W2068393934 hasConcept C188027245 @default.
- W2068393934 hasConcept C2777666793 @default.
- W2068393934 hasConcept C2778659115 @default.
- W2068393934 hasConcept C2780887139 @default.
- W2068393934 hasConcept C3018640491 @default.
- W2068393934 hasConcept C521977710 @default.
- W2068393934 hasConcept C540031477 @default.
- W2068393934 hasConcept C65024703 @default.
- W2068393934 hasConcept C75473681 @default.
- W2068393934 hasConcept C95121573 @default.
- W2068393934 hasConcept C97355855 @default.
- W2068393934 hasConceptScore W2068393934C119889771 @default.
- W2068393934 hasConceptScore W2068393934C121332964 @default.
- W2068393934 hasConceptScore W2068393934C150394285 @default.
- W2068393934 hasConceptScore W2068393934C15920480 @default.
- W2068393934 hasConceptScore W2068393934C161790260 @default.
- W2068393934 hasConceptScore W2068393934C178790620 @default.
- W2068393934 hasConceptScore W2068393934C185592680 @default.
- W2068393934 hasConceptScore W2068393934C188027245 @default.
- W2068393934 hasConceptScore W2068393934C2777666793 @default.
- W2068393934 hasConceptScore W2068393934C2778659115 @default.
- W2068393934 hasConceptScore W2068393934C2780887139 @default.
- W2068393934 hasConceptScore W2068393934C3018640491 @default.
- W2068393934 hasConceptScore W2068393934C521977710 @default.
- W2068393934 hasConceptScore W2068393934C540031477 @default.
- W2068393934 hasConceptScore W2068393934C65024703 @default.
- W2068393934 hasConceptScore W2068393934C75473681 @default.
- W2068393934 hasConceptScore W2068393934C95121573 @default.
- W2068393934 hasConceptScore W2068393934C97355855 @default.
- W2068393934 hasIssue "12" @default.
- W2068393934 hasLocation W20683939341 @default.
- W2068393934 hasOpenAccess W2068393934 @default.
- W2068393934 hasPrimaryLocation W20683939341 @default.
- W2068393934 hasRelatedWork W1978901334 @default.
- W2068393934 hasRelatedWork W1983503423 @default.
- W2068393934 hasRelatedWork W1999039508 @default.
- W2068393934 hasRelatedWork W2026898183 @default.
- W2068393934 hasRelatedWork W2049650886 @default.
- W2068393934 hasRelatedWork W2374462626 @default.
- W2068393934 hasRelatedWork W2377253706 @default.
- W2068393934 hasRelatedWork W2468697832 @default.
- W2068393934 hasRelatedWork W4254801320 @default.
- W2068393934 hasRelatedWork W938367265 @default.
- W2068393934 hasVolume "48" @default.
- W2068393934 isParatext "false" @default.
- W2068393934 isRetracted "false" @default.
- W2068393934 magId "2068393934" @default.
- W2068393934 workType "article" @default.