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- W2068400891 abstract "The rate constants of quenching of CH(A 2Δ) by CHBr3 and CH(A 2Δ and B 2Σ−) by NO, (CH3)2NH, (C2H5)2 and (CH3)3N were measured by using a direct time-resolved technique at 290 K. CH(A 2Δ and B 2Σ−) radicals were produced by laser photolysis of CHBr3 at 266 nm. A mechanism for this photolysis process is proposed. The time-resolved emissions (CH(A→X) and CH(B→X) were monitored as a function of time using a fast digital storage oscilloscope coupled with a microcomputer. For quencher CHBr3, the preliminary result shows that the quenching rate constant decreases with increasing rotational quantum number of CH(A 2Δ, ν′=0). A comparison of the quenching rate constant of CH(A) with that of CH(B) is given." @default.
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- W2068400891 date "1993-02-01" @default.
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- W2068400891 title "Quenching of CH(A 2Δ and B 2Σ−) by NO, CHBr3 and amine molecules" @default.
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- W2068400891 doi "https://doi.org/10.1016/0009-2614(93)85406-e" @default.
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