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• W2068409084 startingPage "584" @default.
• W2068409084 abstract "We report a strategy for the synthesis of side-on liquid crystalline diblock copolymers by a combination of atom transfer radical polymerization (ATRP) method and a macromolecular azo coupling reaction. The liquid crystalline block, with a terminus suitable for azo coupling reaction, was obtained by ATRP using a synthesized ATRP initiator with the designed functional group and a side-on liquid crystalline monomer. The other block, with a diazonium salt terminus, was obtained by the diazotization of aniline-functionalized PEG. The macromolecular azo coupling reactions between above two polymer blocks were carried out in DMF. The products and intermediates were characterized by GPC, 1H NMR, FT-IR, POM and DSC." @default.
• W2068409084 created "2016-06-24" @default.
• W2068409084 creator A5016938126 @default.
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• W2068409084 date "2015-08-01" @default.
• W2068409084 modified "2023-09-23" @default.
• W2068409084 title "Synthesis of side-on liquid crystalline diblock copolymers through macromolecular azo coupling reaction" @default.
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• W2068409084 doi "https://doi.org/10.1016/j.eurpolymj.2015.01.022" @default.
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