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• W2068412684 abstract "B(C6F5)3-catalyzed bis(hydrosilylation) of α-diketones can give high diastereomeric excess of either meso/anti (small silanes and disilane reagents) or dl/syn (bulky silanes) silyl-protected 1,2-diols. This easily tuned diastereoselectivity is rationalized based on the classic Felkin−Anh model applied to a mechanism relying on Si−H abstraction by the electrophilic borane reagent." @default.
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• W2068412684 date "2009-12-16" @default.
• W2068412684 modified "2023-10-16" @default.
• W2068412684 title "Silane-Controlled Diastereoselectivity in the Tris(pentafluorophenyl)borane-Catalyzed Reduction of α-Diketones to Silyl-Protected 1,2-Diols" @default.
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• W2068412684 doi "https://doi.org/10.1021/ol902451h" @default.
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