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• W2068423746 abstract "The synthesis of the bicyclic enediyne compounds 14–18 is described. The bicyclo[7.3.1]trideca-4,9-dien-2,6-diynes (21) are calicheamicin-taxoid mimics, that possess the Taxotere® side chain and an enediyne core. Cyclization of the iodo-aldehyde 13 [CrCl2(THF)2] afforded the bicyclic alcohol 14 as a single diastereomer (76%) and allylic oxidation (SeO2) followed by reaction with the oxazolidine intermediate 19, resolution and hydrolysis provided the taxamycins 21." @default.
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• W2068423746 date "1998-08-01" @default.
• W2068423746 modified "2023-10-09" @default.
• W2068423746 title "Taxamycin studies: Synthesis of taxoid-calicheamicin hybrids" @default.
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• W2068423746 doi "https://doi.org/10.1016/s0040-4039(98)01297-0" @default.
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