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- W2068438093 abstract "Summary The crystal structure of epistilbite ((Ca 2·59 Na 1·06 K 0·10 ) (Al 6·29 Si 17·71 O 48 ).15·74H 2 O; C 2/m; a = 9·08, b = 17·74, c = 10·25±0·01 Å; β = 124·54±0·05°) was determined by 3- D least-squares methods. The alumino-silicate framework is composed of 4-, 5-, and 8-membered rings of tetrahedra. There are two sets of intersecting channels each defined by 8-membered rings. The (Ca, Na) atoms in the channels are in contact with seven water molecules and two oxygen atoms giving a coordination of nine at a cut-off distance of 2·77 Å. The average tetrahedral distance is lower than for anhydrous framework alumino-silicates but consistent with some other zeolite structures. Partial Al-Si ordering exists with one tetrahedron occupied preferentially by aluminum. This tetrahedron contains the two oxygen atoms that are coordinated with the (Ca, Na) atom." @default.
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- W2068438093 date "1967-12-01" @default.
- W2068438093 modified "2023-09-23" @default.
- W2068438093 title "The crystal structure of epistilbite" @default.
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- W2068438093 doi "https://doi.org/10.1180/minmag.1967.036.280.02" @default.
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