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- W2068446502 abstract "From in situ observation of X-ray diffraction of Ni and Pd under a high hydrogen pressure (≃5 GPa) and temperatures (≤800°C), anomalous lattice contraction of the hydride was found to occur in 2∼3 h. This contraction, amounting to ∼0.5 Å 3 per a metal atom, remained in the recovered specimen even after the hydrogen was removed by heating to 400°C, but was annealed out at 800°C. The concentration of vacancies responsible for this effect is estimated at ∼20% of metal-atom sites. Anomalous concentration dependence of the hydrogen-induced volume and enhanced diffusion of metal atoms are explained in terms of this effect." @default.
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- W2068446502 date "1993-09-01" @default.
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- W2068446502 title "Evidence of Copious Vacancy Formation in Ni and Pd under a High Hydrogen Pressure" @default.
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- W2068446502 doi "https://doi.org/10.1143/jjap.32.l1256" @default.
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