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- W2068450815 endingPage "5142" @default.
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- W2068450815 abstract "This paper presents the synthesis and characterization of new homoleptic lithium magnesiate reagents incorporating the silyl-substituted alkyl ligand CH2SiMe3 in the presence of a variety of Lewis base donors, namely tetrahydrofuran (THF), 1,4-dioxane, N,N,N′,N′-tetramethylethylenediamine (TMEDA), and N,N,N′,N″,N″-pentamethyldiethylenetriamine (PMDETA). The constitution of these bimetallic compounds has been assessed in both the solid state and solution using a combination of X-ray crystallographic studies and multinuclear NMR spectroscopy, including 1H diffusion-ordered (1H-DOSY) NMR experiments. These studies highlight the major role played by the donor molecule in controlling the structure of the complexes as well as the wide structural diversity available for these mixed-metal species ranging from discrete molecules, as found for [(PMDETA)LiMg(CH2SiMe3)3] (6), to more complex supramolecular arrangements, as in the 1D-polymeric chain [{(THF)LiMg(CH2SiMe3)3}∞] (2) or in the stoichiometrically distinct d..." @default.
- W2068450815 created "2016-06-24" @default.
- W2068450815 creator A5001903811 @default.
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- W2068450815 creator A5064956572 @default.
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- W2068450815 creator A5091708807 @default.
- W2068450815 date "2012-07-09" @default.
- W2068450815 modified "2023-10-17" @default.
- W2068450815 title "Synthesis, Structural Elucidation, and Diffusion-Ordered NMR Studies of Homoleptic Alkyllithium Magnesiates: Donor-Controlled Structural Variations in Mixed-Metal Chemistry" @default.
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