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- W2068458511 abstract "Abstract Mixtures of a linear polyether, l,13-bis[8-quinolyl]-l,4,7,10,13-pentaoxatridecane, K-5, and thenoyltrifluoroacetone, HTTA, have been shown to exhibit synergistic character in the extraction of trivalent lanthanides and actinides. The effect of the addition of K-5 to the organic phase on the extractions of Ce(III), Eu(III), Tm(III), Am(III), Cm(III), Bk(III), and Cf(III) by HTTA in chloroform from 0.5M NaNO3 at 25°C has been measured. These results indicate the extraction is enhanced by the formation of M(TTA)3K-5 adduct in the organic phase. The organic phase stability constants for the formation of these synergistic species have been calculated for all the metals studied. The magnitude of these organic phase stability constants for K-5 are similar to other common neutral donors. The order of stability does not follow the normal trend based on charge-to-radius ratio, but follows a pattern based on size, with Am(III) being the most stable." @default.
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- W2068458511 date "1984-07-01" @default.
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- W2068458511 title "EXTRACTION OF TRIVALENT LANTHANIDES AND ACTINIDES BY A SYNERGISTIC MIXTURE OF THENOYLTRIFLUOROACETONE AND A LINEAR POLYETHER" @default.
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- W2068458511 doi "https://doi.org/10.1080/07366298408918465" @default.
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