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- W2068458815 abstract "Novel unsymmetrical SCS'-pincer ligands, 1-[PhNHC(S)]-3-[Ph(2)P(S)NH]-C(6)H(4) (3) and 1-[PhNHC(S)]-3-[Ph(2)P(S)O]C(6)H(4) (7), bearing a thiocarbamoyl moiety in combination with thiophosphorylamino- and thiophosphoryloxy-donating groups, respectively, were obtained via thiophosphorylation of 3-amino- and 3-hydroxy-benzoic acid (thio)anilides 1 and 6. Direct cyclometallation of the central benzene ring in the ligands 3 and 7 in reaction with (PhCN)(2)MCl(2) (M = Pd, Pt) as a metal precursor afforded κ(3)-SCS'-hybrid pincer complexes 8, 9 with 5- and 6-membered fused metallacycles in good to high yields (67-95%). The complexes 8 and 9 were characterized by multinuclear NMR ((31)P, (1)H, (13)C) and IR spectroscopy as well as single-crystal X-ray crystallography. Palladium complexes 8a and 9a were shown to be active catalysts for the Suzuki-Miyaura cross-coupling reaction. In the solid state the ligands 3 and 7 as well as their Pt(II) and Pd(II) complexes 8 and 9 are luminescent at 300 K. The emission of the complexes has the different origin depending on the metal nature." @default.
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- W2068458815 date "2011-01-01" @default.
- W2068458815 modified "2023-09-25" @default.
- W2068458815 title "Synthesis, catalytic activity, and photophysical properties of 5,6-membered Pd and Pt SCS′-pincer complexes based on thiophosphorylated 3-amino(hydroxy)benzoic acid thioanilides" @default.
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- W2068458815 doi "https://doi.org/10.1039/c0dt01154a" @default.
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