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- W2068470891 abstract "Chiral liquid crystalline (LC) substituent with fluorine-containing asymmetric moiety was introduced into the 3-position of thiophene ring. Polythiophene derivatives were fusible and soluble in ordinary organic solvents. Phase transition behaviors of the polymers and monomers were examined by differential scanning calorimetry, polarizing optical microscope, and X-ray diffraction. The polymers showed several types of smectic phases in the heating and cooling processes. Besides, one of the polymers exhibited a chiral smectic C phase (Sc*), which is indispensable for ferroelectricity. The ferroelectric behavior was also confirmed by examining the temperature dependence of dielectric constant of the polymer." @default.
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- W2068470891 date "2001-03-01" @default.
- W2068470891 modified "2023-10-18" @default.
- W2068470891 title "Ferroelectric liquid crystalline polythiophene derivatives" @default.
- W2068470891 doi "https://doi.org/10.1016/s0379-6779(00)01398-9" @default.
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