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- W2068471058 abstract "The excitation of NO−3 ions in dilute aqueous solution (10−2 mol.1−1) between 290 and 350 nm in the presence of phenol (10−3 mol.1−1) leads to the formation of the three dihydroxybenzenes, 2- and 4-nitrophenols, hydroxyhydroquinone, benzoquinone, hydroxybenzoquinone, 4-nitrosophenol, 4-nitrocatechol and nitrohydroquinone. The relative importance of the different reactions was evaluated at a low conversion rate. A radical mechanism involving OH and phenoxyl radicals is suggested. The low stationary concentration of hydroquinone, compared with the accumulation of catechol, is attributed to a secondary photochemical reaction of hydroquinone with NO−3." @default.
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- W2068471058 date "1988-01-01" @default.
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- W2068471058 title "Phototransformation of phenol induced by excitation of nitrate ions" @default.
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