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• W2068477307 abstract "The chemical origins of the Hofmeister series are investigated using infrared photodissociation (IRPD) spectroscopy. IRPD spectra of SO42−(H2O)n with up to 80 water molecules have a band at ∼3710 cm−1 for n > 43 but not for n ≤ 43. This band corresponds to outer-shell water molecules with “free” OH groups similar to those at the surface of bulk water. These results indicate that the sulfate dianion has a long-range effect on water structure, and this effect is likely to be an important factor in its Hofmeister behavior." @default.
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• W2068477307 date "2010-06-02" @default.
• W2068477307 modified "2023-10-01" @default.
• W2068477307 title "Sulfate Ion Patterns Water at Long Distance" @default.
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• W2068477307 doi "https://doi.org/10.1021/ja1024113" @default.
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