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• W2068481010 abstract "The Pummerer rearrangement of 1-deoxy-5-thioglucopyranose derivatives carrying acetonides at the C3,4-positions proceeded regioselectively at the C1 position by treating with TFAA in the presence of pyridine. Studies employing deuterium-labelled derivatives revealed that the reaction was induced by E2 1,2-elimination of trifluoroacetic acid of the trifluoroacetoxy sulfonium intermediate. This methodology was applied to the synthesis of an isomaltotriose derivative consisting of 5-thioglucopyranoside units." @default.
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• W2068481010 date "2004-08-01" @default.
• W2068481010 modified "2023-09-22" @default.
• W2068481010 title "Synthesis of thiosaccharides employing the Pummerer rearrangement of tetrahydrothiopyran oxides" @default.
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• W2068481010 doi "https://doi.org/10.1016/j.tet.2004.06.006" @default.
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