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- W2068500736 abstract "Rh(2)(S-DOSP)(4)-catalyzed decomposition of heteroaryldiazoacetates in the presence of styrene results in highly diastereoselective and enantioselective cyclopropanations. Heteroaryldiazoacetates containing both electron-rich and electron-deficient heterocycles, such as thiophene, furan, pyridine, indole, oxazole, isoxazole, and benzoxazole, are effective in this chemistry. These studies broaden the range of diazo compounds containing both electron-withdrawing and electron-donating groups, which undergo highly diastereoselective cyclopropanations." @default.
- W2068500736 created "2016-06-24" @default.
- W2068500736 creator A5029454118 @default.
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- W2068500736 date "2001-08-30" @default.
- W2068500736 modified "2023-10-18" @default.
- W2068500736 title "Catalytic Asymmetric Cyclopropanation of Heteroaryldiazoacetates" @default.
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- W2068500736 doi "https://doi.org/10.1021/jo015617t" @default.
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