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• W2068508129 abstract "Total cross sections for electron scattering on ${mathrm{CH}}_{3}mathrm{Cl},{mathrm{CH}}_{2}{mathrm{Cl}}_{2},$ and ${mathrm{CHCl}}_{3}$ have been measured by an absolute method in the (75--4000)-eV energy range. The overall experimental error is below 5%. A formulation of the additivity rule is proposed. The molecular cross sections are approximated by a Born-like two-parameter formula. We show that the low-energy parameter is correlated to the molecular polarizability. We show also that the high-energy parameter for a given molecule can be expressed as the sum of the high-energy parameters of the constituent atoms. The model has been successfully verified for two groups of halomethanes: the ${mathrm{CH}}_{4},{mathrm{CH}}_{3}mathrm{Cl},{mathrm{CH}}_{2}{mathrm{Cl}}_{2},{mathrm{CHCl}}_{3},$ and ${mathrm{CCl}}_{4}$ series and the ${mathrm{CF}}_{4},{mathrm{CF}}_{3}mathrm{Cl},{mathrm{CF}}_{2}{mathrm{Cl}}_{2},{mathrm{CFCl}}_{3},$ and ${mathrm{CCl}}_{4}$ series. The model has been successfully extended to molecules containing Si and S atoms, such as ${mathrm{H}}_{2}mathrm{S},{mathrm{SF}}_{6},{mathrm{SiH}}_{4},$ and ${mathrm{SiF}}_{4}.$" @default.
• W2068508129 created "2016-06-24" @default.
• W2068508129 creator A5006190112 @default.
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• W2068508129 date "1999-02-01" @default.
• W2068508129 modified "2023-09-27" @default.
• W2068508129 title "Total cross sections for electron scattering on chloromethanes: Formulation of the additivity rule" @default.
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• W2068508129 doi "https://doi.org/10.1103/physreva.59.1341" @default.
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