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- W2068517188 abstract "Abstract Trifluoroacetolysis of d -glucuronic acid and methyl α- d -glucopyranosiduronic acid resulted in an initial phase of degradation followed by stabilisation of the compounds as their 6,3-lactones. The methyl ester of methyl 4-O-methyl-α- d -glucopyranosiduronic acid was largely stable towards trifluoroacetolysis. Aldonic acids substituted at O-3 or O-6 were stable towards trifluoroacetolysis because of the formation of γ-lactones. Aldonic acids substituted at O-4, and incapable of forming γ-lactones, were converted into the trifluoroacetylated enol of 3-deoxy-2-hexulosonic acid. Treatment of the 3-deoxy-2-hexulosonic acid with mild base eliminated the substituent at O-4." @default.
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- W2068517188 date "1984-09-01" @default.
- W2068517188 modified "2023-09-24" @default.
- W2068517188 title "The reactivity of uronic and aldonic acid derivatives towards trifluoroacetolysis. A new method for specific elimination of reducing 4-O-substituted hexose residues" @default.
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- W2068517188 doi "https://doi.org/10.1016/0008-6215(84)85063-6" @default.
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