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• W2068553971 abstract "Sm filled CoSb3 without charge compensation was synthesized at ambient pressure for the first time through a melt-annealing method. The synthetic SmyCo4Sb12 samples possess an Im3¯ symmetry of skutterudite structure. The lattice parameter expanded mildly after Sm inclusion into CoSb3 lattice. A larger atomic displacement parameter (ADP) was revealed for Sm atoms compared with those of Co and Sb atoms, indicating the rattling mode of Sm atoms inside the oversized cages. The thermoelectric property investigations revealed a significantly depressed thermal conductivity caused by the strong phonon scattering from loosely bond Sm fillers while maintaining high electrical performance. As a result, the maximum ZT value of 0.8 was achieved at 716 K for Sm0.6Co4Sb12 sample." @default.
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• W2068553971 date "2015-03-01" @default.
• W2068553971 modified "2023-10-16" @default.
• W2068553971 title "Structural and thermoelectric characterizations of samarium filled CoSb3 skutterudites" @default.
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• W2068553971 doi "https://doi.org/10.1016/j.matlet.2014.12.019" @default.
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