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- W2068574940 abstract "Azo-functionalized calix[4]arenes as ionophores for chloride-selective electrode, 5,11,17,23-Tetra-tert-butyl-25,27-bis[(N,N-dimethyl-aniline-azo-phenylthioureido)ethyl]oxy-26,28-dihydroxycalix[4]arene (4a) and 5,11,17,23-Tetra-tert-butyl-25,27-bis[(N,N-dimethyl-aniline-azo-phenylthioureido)ethyl]oxy-26,28-dimethoxycalix[4]arene (4b) were synthesized. The PVC membrane electrode based on azo-functionalized calix[4]arene 4a with o-NPOE exhibits a linear stable response over a wide concentration range (1.5 x 10 - 4 -1.0 x 10 - 1 ) with a slope of -52.0 mV/decade and a detection limit of log[Cl - ] = -4.02. This ionophore-based membrane exhibited improved selectivity for chloride anion compared with classical Hofmeister series." @default.
- W2068574940 created "2016-06-24" @default.
- W2068574940 date "2003-12-20" @default.
- W2068574940 modified "2023-10-17" @default.
- W2068574940 title "Synthesis of Azo-functionalized Calix[4]arenes and Its Application to Chloride-selective Electrode as Ionophores" @default.
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- W2068574940 doi "https://doi.org/10.5012/bkcs.2003.24.12.1737" @default.
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