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- W2068575672 abstract "2-Acetoxy-2-methoxy-5,5-dimethyl-Δ 3 -1,3,4-oxadiazoline undergoes two competitive 1,3-dipolar cycloreversions at 110 °C. It loses N 2 , presumably to afford a short-lived carbonyl ylide that fragments to acetone and acetoxy(methoxy)carbene. It also forms 2-diazopropane and the appropriate mixed anhydride. It is the only currently known source of acetoxy(methoxy)carbene. Key words: acetoxy(methoxy)carbene, 2-diazopropane, 1,3-dipolar cycloreversion." @default.
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- W2068575672 date "2003-12-01" @default.
- W2068575672 modified "2023-10-18" @default.
- W2068575672 title "2-Acetoxy-2-methoxy-5,5-dimethyl-Δ<sup>3</sup>-1,3,4-oxadiazoline and acetoxy(methoxy)carbene" @default.
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- W2068575672 doi "https://doi.org/10.1139/v03-126" @default.
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