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- W2068581671 abstract "Abstract This article reports on the transformation of santonin into two C10-epimeric 3-oxa-guaianolides which are 8-deoxyderivatives of several natural 3-oxaguaianolides isolated from Achillea species. The synthesis involved the photochemical rearrangement of the eudesmane skeleton into a guaiane skeleton and the transformation of the cyclopentane ring into a furan moiety with the concomitant loss of C3. Comparison of the NMR data of the synthetic products with those of the natural products confirms the β orientation of the hydroxyl group at C10 in the products isolated from Achillea." @default.
- W2068581671 created "2016-06-24" @default.
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- W2068581671 date "2000-08-18" @default.
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- W2068581671 title "Synthesis of 3-Oxa-guaianolides from Santonin" @default.
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- W2068581671 doi "https://doi.org/10.1016/s0040-4020(00)00571-8" @default.
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