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- W2068582904 abstract "A process for the efficient conversion of trimethylsulfonium methylsulfate into dimethylsulfonium methanide, thence epoxides, has been devised. Thus dimethyl sulfate and dimethyl sulfide are caused to react in the presence of either a mineral acid or an organic acid. The anion of trimethylsulfonium methyl sulfate is converted by the acid into methyl hydrogen sulfate, which in turn reacts with excess dimethyl sulfide to form trimethylsulfonium hydrogen sulfate. The outcome is that both methyl groups of dimethyl sulfate are converted into the desired trimethylsulfonium salt, thence dimethylsulfonium methanide; the process is mediated by low boiling dimethyl sulfide which can be recycled, and the by-product (K2SO4) is more easily disposed of than potassium methyl sulfate." @default.
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- W2068582904 date "1999-01-01" @default.
- W2068582904 modified "2023-09-24" @default.
- W2068582904 title "Efficient use of trimethylsulfonium methylsulfate as a reagent for the epoxidation of carbonyl-containing compounds" @default.
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- W2068582904 doi "https://doi.org/10.1039/a907053b" @default.
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