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• W2068590003 abstract "Pd on activated carbon (Pd/C) is demonstrated to be active and selective as one single catalyst in a series of one-pot multi-step reactions. The carefully chosen Pd/C catalysts were successfully applied in domino and tandem reactions involving (1) Heck reactions and hydrogenations for the synthesis of (a) dibenzyl and (b) 2-styryl-phenylamine, (2) Sonogashira coupling and intramolecular heteroannulation to form indole ring systems, and (3) Heck and Suzuki coupling reactions to produce 4-styryl-biphenyl. Total yields between 72 and 93% could be achieved. All reaction steps were performed with one and the same Pd/C catalyst, solvent, and additives. Temperature and pressure were adjusted as necessary. The order of the different reactions, the consecutive addition of educt(s) and optimization of reaction conditions was found to be crucial." @default.
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• W2068590003 date "2004-07-08" @default.
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• W2068590003 title "Palladium on activated carbon: a valuable heterogeneous catalyst for one-pot multi-step synthesis" @default.
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• W2068590003 doi "https://doi.org/10.1016/j.apcata.2004.01.012" @default.
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