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• W2068600972 abstract "Chiral recognition is a fundamental phenomenon in life sciences based on the enantioselective complexation of a chiral molecule with a chiral selector. The diastereomeric aggregates, formed by complexation, are held together by a different combination of intermolecular forces and are, therefore, endowed with different stability and reactivity. Determination of these forces, which are normally affected in the condensed phase by solvent and supramolecular interactions, requires the generation of the diastereomeric complexes in an isolated state and their kinetic and spectroscopic investigation. This paper concerns enantiodiscrimination of chiral molecules in the gas phase through the application of various ESI-MSn-CID and REMPI-TOF methodologies. The measurement of the fragmentation thresholds of diastereomeric clusters by these techniques allowed to shed light upon the nature and the magnitude of the intrinsic interactions which control their formation and which affect their stability and reactivity." @default.
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• W2068600972 date "2003-01-01" @default.
• W2068600972 modified "2023-10-11" @default.
• W2068600972 title "Gas-phase complexes: noncovalent interactions and stereospecificity" @default.
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• W2068600972 doi "https://doi.org/10.1016/s1387-3806(02)00787-x" @default.
• W2068600972 hasPublicationYear "2003" @default.
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