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- W2068604474 abstract "Abstract The electrooxidation of phenylacetylene (PA) in acetonitrile (0.1 M in LiClO 4 ) produced poly(phenylacetylene). The product was isolated, purified, and characterized. Spectroscopic data showed the trans structure of the polymer. A radical reaction mechanism was proposed in which the oxidation of PA led to the formation of a PA radical in solution, which initiated a radical polymerization. The theoretical treatment for the radical mechanism yielded a reaction rate equation identical to the experimental one. The average molar mass was determined by gel permeation chromatography to be approximately 3100. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 2407–2416, 2005" @default.
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- W2068604474 date "2005-04-25" @default.
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- W2068604474 title "Electropolymerization of phenylacetylene in acetonitrile" @default.
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- W2068604474 doi "https://doi.org/10.1002/pola.20713" @default.
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