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- W2068607218 abstract "Two new salts, [2-NaMePy]2[Ni(i-mnt)2] (1) and [2-NaMe-4-MePy]2[Ni(i-mnt)2] (2) ([2-NaMePy]+ = 1-(2′-naphthylmethyl)pyridinium, [2-NaMe-4-MePy]+ = 1-(2′-naphthylmethyl)-4-methylpyridinium and i-mnt2− = iso-maleonitriledithiolate), have been prepared and characterized by elemental analyses, UV, IR, molar conductivity, and single crystal X-ray diffraction. The anions in 1 form a 1-D chain through short C ··· N interactions between the anions, while the cations in 2 stack a 1-D column via C–H ··· π and π ··· π stacking interactions between the cations. The effect of weak intramolecular interactions such as C–H ··· N, C–H ··· S, C–H ··· Ni hydrogen bonds, and π ··· π stacking interactions between the cations and the anions further generate a 3-D network structure. The change of the molecular topology of the countercation when the 4-substituted group in the pyridine ring is changed from H atom to CH3 group results in different crystal system, space group, and the stacking mode of the cations and anions of 1 and 2." @default.
- W2068607218 created "2016-06-24" @default.
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- W2068607218 date "2009-05-13" @default.
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- W2068607218 title "Syntheses, weak interactions, and 3-D network structures of two salts based on [Ni(i-mnt)2]2− (i-mnt2−=iso-maleonitriled-ithiolate) anion with substituted pyridinium cation" @default.
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- W2068607218 doi "https://doi.org/10.1080/00958970902755418" @default.
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