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- W2068610408 abstract "An efficient two-step synthesis of some fluoro pyruvic acids monohydrates 6 is described. The reaction of fluoromethyltrimethylsilanes 3 with di-tert-butyl oxalate (4) in the presence of tetrabutylammonium fluoride as a catalyst produces intermediate siloxy products 5, which are converted by hydrogen chloride into 6. 3,3,4,4,4-Pentafluoro-2-oxo-butanoic acid monohydrate (6c) is obtained analogously by reacting pentafluoroethyltrimethylsilane (3c) with 4." @default.
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- W2068610408 date "1990-03-01" @default.
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- W2068610408 title "Fluorierte α-Oxocarbonsäuren aus Oxalsäuredi-tert-butylester und fluorierten (Halo)alkyltrimethylsilanen / Fluorinated a-Oxocarboxylic Acids from Oxalic Di-tert-butylester and Fluoro(halo)alkyltrimethylsilanes" @default.
- W2068610408 doi "https://doi.org/10.1515/znb-1990-0317" @default.
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