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- W2068641628 abstract "We report time-resolved fluorescence data for the anion of p-hydroxybenzylidene dimethylimidazolinone (p-HBDI), a model chromophore of the green fluorescence protein, in viscous glycerol−water mixtures over a range of temperatures, T. The markedly nonexponential decay of the excited electronic state is interpreted with the aid of an inhomogeneous model possessing a Gaussian coordinate-dependent sink term. A nonlinear least-squares fitting routine enables us to achieve quantitative fits by adjusting a single activation parameter, which is found to depend linearly on 1/T. We derive an analytic expression for the absolute quantum yield, which is compared with the integrated steady-state fluorescence spectra. The microscopic origins of the model are discussed in terms of two-dimensional dynamics, coupling the phenyl-ring rotation to a swinging mode that brings this flexible molecule to the proximity of a conical intersection on its multidimensional potential energy surface." @default.
- W2068641628 created "2016-06-24" @default.
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- W2068641628 date "2006-02-14" @default.
- W2068641628 modified "2023-09-27" @default.
- W2068641628 title "Deactivation Mechanism of the Green Fluorescent Chromophore" @default.
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- W2068641628 doi "https://doi.org/10.1021/jp0540095" @default.
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