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- W2068656929 endingPage "1973" @default.
- W2068656929 startingPage "1971" @default.
- W2068656929 abstract "The equilibrium between [Ce(H2O)9]3+ and [Ce(H2O)8]3+ has been followed in aqueous solution at 298 K by variable-pressure UV spectroscopy at 295 nm. The dervied volume of reaction for the dissociation of this enneaaqua ion is ΔV0 = +10.9 cm3. mol−1. This value, together with the previously determined activation volume, ΔV≠ = −6 cm3. mol−1, for H2O exchange on [Ln(H2O)8]3+ (Ln = Tb to Tm), allows the assignment of an associative interchange Ia mechanism on these octaaqua ions." @default.
- W2068656929 created "2016-06-24" @default.
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- W2068656929 date "1988-12-14" @default.
- W2068656929 modified "2023-09-30" @default.
- W2068656929 title "The Reaction Volume for the Equilibrium between the Lanthanide (III) ennea- and octaaqua lons as a diagnostic aid for their water-exchange mechanisms. Preliminary Communication" @default.
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- W2068656929 doi "https://doi.org/10.1002/hlca.19880710815" @default.
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